High-temperature pH measuring during hot-water extraction of hemicelluloses from wood

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Jens Krogell, Kari Eränen, Kim Granholm, Andrey Pranovich, Stefan Willför
Publisher: ELSEVIER SCIENCE BV
Publication year: 2014
Journal: Industrial Crops and Products
Journal acronym: IND CROP PROD
Volume number: 61
Start page: 9
End page: 15
Number of pages: 7
ISSN: 0926-6690
eISSN: 1872-633X


Abstract

A high-temperature pH measuring system was developed, calibrated, and validated for measuring pH during hot-water extraction of hemicelluloses from wood. The aim was to measure in-line pH during extraction in order to control the extraction pH. An yttria-stabilized Zr/ZrO2 electrode was used for measuring the potential. Phthalate and phosphate buffers were used to calibrate the system at 160, 170, and 180 degrees C. Also, different buffer concentrations were tested for stability. Tap water and different salt solutions were tested to investigate the system response to pure water and water solutions. Calibration curves were acquired from the calibration results and Nernst equation was used to calculate the in-line pH during wood extractions. The setup showed stable and reliable potential readings during both calibration tests and wood extractions. The in-line pH was found to be 0.35 pH units higher than when measured at room temperature with a conventional pH meter.


Keywords

Hemicelluloses, High-temperature pH, Hot-water extraction, pH calibration, Spruce wood

Last updated on 2019-16-10 at 03:30

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