Kinetic Modeling of Sorbitol Aqueous-Phase Reforming over Pt/Al2O3

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Alexey Kirilin, Johan Wärnå, Anton Tokarev, Dmitry Yu. Murzin
Publication year: 2014
Journal: Industrial & Engineering Chemistry Research
Volume number: 53
Issue number: 12
Start page: 4580
End page: 4588


Abstract

Aqueous-phase reforming of polyols was investigated in the current work by mathematical modeling using sorbitol, which represents a C6-polyol originating from biomass processing. The reaction was studied in the presence of Pt/Al2O3 catalyst at 498 K and 29.3 bar in a continuous fixed-bed reactor under kinetic control. The feasible scheme describing main pathways of sorbitol transformation was proposed considering experimental and literature data. The kinetic model was compared with experimental data through numerical data fitting showing good correspondence.

Last updated on 2019-18-11 at 03:52