[1,5]-Silatropic shifts in disilyl substituted indenes: an NMR spectroscopic and computational study

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Satu Silver, Ville Nieminen, Reko Leino
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2006
Journal: Tetrahedron
Journal acronym: TETRAHEDRON
Volume number: 62
Issue number: 40
Start page: 9417
End page: 9422
Number of pages: 6
ISSN: 0040-4020
eISSN: 1464-5416


Abstract

The equilibrium profiles for [1,5]-silatropic shifts in a series of 1,3-/1,1-disilyl substituted indenes were studied by NMR and computational methods based on density functional theory. Both methods indicate higher activation parameters for the [1,5]-shifts than observed in monosilyl substituted indene analogues.

Last updated on 2019-17-10 at 03:19