The red, purple and blue modifications of polymeric unsymmetrical hydroxyalkadiynyl-N-arylcarbamate derivatives in Langmuir-Schaefer films

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Alexander Alekseev, Petri Ihalainen, Artem Ivanov, Ivan Domnin, Vera Klechkovskaya,
Anton Orekhov, Helge Lemmetyinen, Elina Vuorimaa-Laukkanen, Jouko Peltonen, Sergey Vyaz'min
Publisher: Elsevier
Publication year: 2016
Journal: Thin Solid Films
Volume number: 612
Start page: 463
End page: 471
eISSN: 1879-2731


Abstract

Solid topochemical photopolymerization (STP) of Langmuir-Schaefer films of a new class of unsymmetrical diynes, containing N-arylcarbamate groups in the hydrophobic part and hydroxymethylene groups in the hydrophilic part of the moleculeswas examined. In addition, the monomeric Langmuir monolayer formation was studied by Brewster angle microscopy and the surface morphology of monomer and polymer films on solid substrates were studied by scanning electron microscopy and atomic force microscopy. Three phases of polydiacetylene (PDA) (red, purple and blue) were observed after UV-light polymerization of above-mentioned films of alcohol
diacetylene (DA) derivatives. The substitution of MeO group in the aryl ring substituent by hydrogen atom and the variation of the methylene group number in the hydrophobic part from 5 to 6 changed significantly the result of STP: instead of blue phase PDA observed for diynes with MeO group, the red phase PDA was observed for DA with H-atom from the very beginning of diyne film UV irradiation. For two other diynilic N-arylcarbamates of identical chemical structures except of the substituents in the aryl ring of hydrophobic parts of the molecules, no changes in the efficiency of polymerization or the position and shape of absorption bands were observed. This indicated the formation of the purple phase PDA. For these molecules, the number of methylene groups in hydrophobic and hydrophilic parts of the molecules was 9 and 2, respectively.


Keywords

acetylene, monolayer, surface topography, synthesis, Topochemistry, UV-vis absorption

Last updated on 2019-16-10 at 02:41