Selective hydrogenation of fatty acids to alcohols over highly dispersed ReOₓ/TiO₂ catalyst

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Bartosz Rozmysłowicz, Alexey Kirilin, Atte Aho, Haresh Manyar, Christopher Hardacre, Johan Wärnå, Tapio Salmi, Dmitry Yu. Murzin
Publiceringsår: 2015
Tidskrift: Journal of Catalysis
Volym: 328
Nummer: SI
Artikelns första sida, sidnummer: 197
Artikelns sista sida, sidnummer: 207
eISSN: 1090-2694


Abstrakt

Production of fatty alcohols through selective hydrogenation of fatty acids was studied over a 4% ReOx/TiO2 catalyst. Stearic acid was hydrogenated to octadecanol at temperatures and pressures between 180–200 °C and 2–4 MPa, with selectivity reaching 93%. A high yield of octadecanol was attributed to a strong adsorption of the acid compared to alcohol on the catalyst, which inhibits further alcohol transformation to alkanes. Low amounts (<7%) of alkanes (mainly octadecane) were formed during the conversion of stearic acid. However, it was found that the catalyst could be tuned for the production of alkanes. The reaction intermediates were octadecanal and stearyl stearate. Based on the reaction products analysis and catalyst characterization, a reaction mechanism and possible pathways were proposed.



Senast uppdaterad 2019-19-10 vid 03:12