Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Yury Brusentsev, Patrik Eklund
Publisher: Georg Thieme Verlag KG
Publication year: 2016
Journal: Synlett
Volume number: 27
Issue number: 18
Start page: 2557
End page: 2560
eISSN: 1437-2096


Abstract

Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.


Keywords

chiral 1,4-diols, chiral phosphates, chiral phosphites, chiral pool, conidendrin, Lignan, matairesinol

Last updated on 2019-14-10 at 04:05