Pd supported IRMOF-3: Heterogeneous, efficient and reusable catalyst for Heck reaction

A1 Journal article (refereed)

Internal Authors/Editors

Publication Details

List of Authors: Ayat Nuri, Nemanja Vucetic, Jan-Henrik Smått, Yagoub Mansoori, Jyri-Pekka Mikkola, Dmitry Yu Murzin
Publisher: Springer
Publication year: 2019
Journal: Catalysis Letters
Journal acronym: Catal. Lett.
Volume number: 149
Start page: 1941
End page: 1951
ISSN: 1572879X 1011372X
eISSN: 1572-879X


IRMOF-3 with a high surface area prepared by a hydrothermal method was used for deposition of Pd(OAc)2 on IRMOF-3 particles. The final catalyst was characterized with FT-IR, nitrogen physisorption, thermogravimetry, scanning electron microscopy, transmission electron microscopy combined with energy dispersive X-ray analysis, wide angle X-ray diffraction spectroscopy and X-ray photoelectron spectroscopy. The prepared porous catalyst was effectively used in the Heck coupling reaction in the presence of an organic base. The reaction parameters such as the type of base, amounts of catalyst and solvents, temperature were optimized. The catalyst was then easily separated, washed, and reused 4 times without significant losses of catalytic activity.


Heck reaction, IRMOF-3-Pd, Metal–organic-frameworks

Last updated on 2020-30-03 at 08:23