Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Alexandrina Sulman, Päivi Mäki-Arvela, Louis Bomont, Moldir Alda-Onggar, Vyacheslav Fedorov, Vincenzo Russo, Kari Eränen, Markus Peurla, Uliana Akhmetzyanova, Lenka Skuhrovcová, Zdeněk Tišler, Henrik Grénman, Johan Wärnå, Dmitry Yu. Murzin
Publication year: 2019
Journal: Catalysis Letters
Journal acronym: Catal. Lett.
Volume number: 149
Issue number: 9
Start page: 2453
End page: 2467
eISSN: 1572-879X


Abstract

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.


Last updated on 2020-08-04 at 04:16

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