Kinetic and thermodynamic analysis of guaiacol hydrodeoxygenation

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Alexandrina Sulman, Päivi Mäki-Arvela, Louis Bomont, Moldir Alda-Onggar, Vyacheslav Fedorov, Vincenzo Russo, Kari Eränen, Markus Peurla, Uliana Akhmetzyanova, Lenka Skuhrovcová, Zdeněk Tišler, Henrik Grénman, Johan Wärnå, Dmitry Yu. Murzin
Publiceringsår: 2019
Tidskrift: Catalysis Letters
Tidskriftsakronym: Catal. Lett.
Volym: 149
Nummer: 9
Artikelns första sida, sidnummer: 2453
Artikelns sista sida, sidnummer: 2467
eISSN: 1572-879X


Abstrakt

Kinetics of guaiacol hydrodeoxygenation (HDO) was studied using supported MoxC–SBA-15 and as a comparison 5 wt% Pt/C under 30 bar hydrogen at 200 °C and 300 °C. Catalyst characterization was done by a range of physical methods including also determination of the amount of coke and the nature of adsorbed species. Pt/C gave 2-methoxycyclohexanol as the main product, whereas Mo2C–SBA-15 promoted direct deoxygenation exhibiting also strong adsorption of guaiacol on the catalyst surface and formation of oligomers. Thermodynamics of guaiacol HDO was elucidated and the reaction network was proposed based on which kinetic modelling was done.


Senast uppdaterad 2020-19-02 vid 03:38