Biocrude production through hydro‐liquefaction of wood biomass in supercritical ethanol using iron silica and iron beta zeolite catalysts

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Ramakrishna Jogi, Päivi Mäki-Arvela, Pasi Virtanen, Narendra Kumar, Jarl Hemming, Annika Smeds, Torbjörn A Lestander, Jyri-Pekka Mikkola
Publication year: 2019
Journal: Journal of Chemical Technology and Biotechnology
Journal acronym: J. Chem. Technol. Biotechnol.
Volume number: 94
Issue number: 11
Start page: 3736
End page: 3744
eISSN: 1097-4660


Abstract

BACKGROUND: In the production of biofuels from lignocellulosic material, biocrude plays a key role. The present work deals with the biocrude production through hydrothermal liquefaction (HTL) of birch wood in supercritical ethanol over 5 wt% Fe-H-Beta-150 (SiO2 to Al2O3 ratio of 150) or 5 wt% Fe-SiO2 catalyst.

RESULTS: The liquid and solid products were characterized with various analytical techniques such as gas chromatography mass spectrometry (GC–MS), gas chromatography with a flame ionization detector (GC-FID), size exclusion chromatography (SEC), inductively-coupled plasma mass spectrometry (ICP-MS), powder X-ray diffraction (p-XRD), scanning electron microscopy (SEM), and solid-state carbon-13 magic angle spinning nuclear magnetic resonance (13C-MAS-NMR), respectively. The results revealed that 5 wt% Fe-H-Beta-150, a strongly Brønsted acidic catalyst, enhanced the biocrude formation when compared with a non-acidic 5 wt% Fe-SiO2 catalyst. Hemicellulose and lignin degradation occurred resulting in formation of mainly sugars, acids-esters and phenolic compounds in the liquid phase. The gaseous atmosphere of hydrogen also enhanced the degradation of biomass. The biocrude yield from birch was 25wt% over 5 wt% Fe-H-Beta-150. The Brønsted acidic catalyst gave higher dissolution efficiency and its clear catalytic effect was observed in comparison to non-acidic 5 wt% Fe-SiO2. The degradation level of lignin in the presence of 5 wt% Fe-H-Beta-150 was high 68wt% aromatic products were formed, while only 38wt% was obtained with 5 wt% Fe-SiO2.

CONCLUSIONS: Hydrogen atmosphere enhances the fractionation of birch wood when compared to argon atmosphere. The 5wt% Fe-H-Beta-150 catalyst enhanced very strongly the degradation of hemicellulose and lignin in biomass to sugars and acid-esters as well as phenolic compounds, respectively, compared to the non-acidic 5 wt% Fe-SiO2 catalyst.


Keywords

Birch wood, hydrothermal liquefaction

Last updated on 2020-04-07 at 04:33