All-solid-state Ag+-ISE based on [2.2.2]p,p,p-cyclophane

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Bobacka J, Lahtinen T, Nordman J, Haggstrom S, Rissanen K, Lewenstam A, Ivaska A
Publisher: WILEY-V C H VERLAG GMBH
Publication year: 2001
Journal: Electroanalysis
Journal acronym: ELECTROANAL
Volume number: 13
Start page: 723
End page: 726
Number of pages: 4
ISSN: 1040-0397


Abstract

All-solid-state ion-selective electrodes (ISEs) based on two ionophores with similar structure, i.e., [2.2.2] p,p,p-cyclophane and [2.2.2]m,p,p-cyclophane, were prepared and investigated. The ion-selective membranes were composed of the corresponding ionophore (1%), potassium tetrakis(4-chlorophenyl)borate (0.5%), 2-nitrophenyl octyl ether (65-66%), and PVC (33%). The ion-selective membrane was placed on top of a layer of the ct inducting polymer, poly(3,4-ethylenedioxythiophene) (PEDOT), working as ion-to-electron transducer. The resulting all-solid-state ISEs were conditioned in 0.01 M AgNO3 and investigated as Ag+-ISEs. The results show that [2.2.2]p,p,p-cyclophane is much more selective to Ag+ than [2.2.2]m,p,p-cyclophane.


Keywords

all-solid-state, cyclophane, silver ion

Last updated on 2019-13-12 at 04:26