Catalytic conversion of hexanol to 2-butyl-octanol through the Guerbet reaction

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Frans Storgårds, Päivi Mäki-Arvela, Narendra Kumar, Janne Peltonen, Jarno Salonen, Markus Perula, Kari Eränen, Vincenzo Russo, Dmitry Yu. Murzin, Henrik Grénman
Publication year: 2018
Journal: Topics in Catalysis
Journal acronym: Top. Catal.
Volume number: 61
Issue number: 18-19
Start page: 1888
End page: 1900
eISSN: 1572-9028


Abstract

Activity of heterogeneous catalysts for synthesis of Guerbet alcohols from hexanol was evaluated. Commercial synthetic hydrotalcite (HT) was used in the aldol condensation reaction, which is a part of the Guerbet reaction network. HTs were calcined at different temperatures in order to modify their basicity and additionally, NaOH was applied in some experiments as a homogeneous base. The homogeneous base proved to be more efficient in aldol condensation experiments, while HT also performed in an acceptable way. Bi-functional metal containing HTs were synthesized by wet impregnation and co-precipitation methods employing different active metals. The materials were characterized with a number of methods, including CO2-TPD, pyridine-FTIR, nitrogen physisorption, transmission electron microscopy, SEM–EDX and XRD. Copper containing catalysts produced hexyl-hexanoate with a very high selectivity, while Ni-containing counterparts exhibited the highest selectivity towards the Guerbet alcohol. The co-precipitated catalysts were more active in the current study than the ones produced by wet-impregnation. Nevertheless, synthesis of Guerbet alcohols from hexanol with a one-pot method proved to be challenging, with the best yield of the Guerbet product in 24 h being 5%. This is proposed to be largely due to thermodynamic limitations, which was confirmed by calculations of thermodynamics.


Keywords

Chemical Engineering

Last updated on 2019-14-11 at 04:21