Impact of Torrefaction on the Chemical Structure of Birch Wood

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Shoulaifar TK, DeMartini N, Willfor S, Pranovich A, Smeds AI, Virtanen TAP, Maunu SL, Verhoeff F, Kiel JHA, Hupa M
Förläggare: AMER CHEMICAL SOC
Publiceringsår: 2014
Tidskrift: Energy and Fuels
Tidskriftsakronym: ENERG FUEL
Volym: 28
Nummer: 6
Artikelns första sida, sidnummer: 3863
Artikelns sista sida, sidnummer: 3872
Antal sidor: 10
ISSN: 0887-0624


Abstrakt

Torrefaction is the thermal pretreatment of biomass at temperatures of 200-300 degrees C in an inert atmosphere with the objectives of improving resistance to biodegradation, reducing hydrophilicity, improving grindability and increasing energy density. In this work, we studied the effect of torrefaction temperature (240-280 degrees C) on the chemistry of birch wood. The samples were from a pilot plant at ECN, and in that way, they were representative of industrially produced samples. We have measured the concentration of hemicellulose and cellulose; changes in the extractives content and composition; and in the lignin structure. We used acid methanolysis and acid hydrolysis for hemicellulose and cellulose analysis, respectively; Klason lignin method, C-13 CP-MAS NMR, Dipolar Dephasing NMR, and Py-GC-MS analysis for lignin characterization; and acetone extraction, HPSEC, GC-FID, and GC-MS analysis for extractives characterization. The results provide a more complete picture of the chemical changes in wood by torrefaction.

Senast uppdaterad 2019-12-12 vid 03:18