Indenyl esters as potential electronically modified cyclopentadienyl ligands for transition metal complexes

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Leino R, Luttikhedde HJG, Langstedt L, Penninkangas A
Publisher: PERGAMON-ELSEVIER SCIENCE LTD
Publication year: 2002
Journal: Tetrahedron Letters
Journal acronym: TETRAHEDRON LETT
Volume number: 43
Issue number: 23
Start page: 4149
End page: 4151
Number of pages: 3
ISSN: 0040-4039


Abstract

The preparation of two new indenyl esters 2-(2,4,6-trimethylbenzoyloxy)indene (1) and 2-(adamantanoyloxy)indene (2) is reported. Both compounds can be deprotonated with alkyllithiums such as n-BuLi and the resulting anions trapped by addition of TMSCl or iodomethane, rendering them as potential electronically modified cyclopentadienyl ligand analogues for complexation with transition metals. (C) 2002 Elsevier Science Ltd. All rights reserved.

Last updated on 2019-18-10 at 02:49