A chiral diamine bis-phenolate complex of dioxomolybdenum(VI)

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Manian RDRS, Leino R, Wichmann O, Lehtonen A
Publisher: ELSEVIER SCIENCE BV
Publication year: 2009
Journal: Inorganic Chemistry Communications
Journal acronym: INORG CHEM COMMUN
Volume number: 12
Issue number: 10
Start page: 1004
End page: 1006
Number of pages: 3
ISSN: 1387-7003


Abstract

A new dioxomolybdenum(VI) complex with a chiral tetradentate ligand is reported. The tripodal ligand containing two nitrogen atoms and two phenolic oxygen atoms was synthesized starting from a chiral diamine precursor. Further reaction with [MoO(2)(acac)(2)] yielded a monomeric molybdenum complex as a bright yellow solid. The structures of the molybdenum complex and the free diamine bis-phenol ligand were determined by X-ray diffraction. (C) 2009 Elsevier B.V. All rights reserved.


Keywords

Chiral ligands, Molybdenum, Oxo complexes, Phenolate ligands

Last updated on 2019-20-10 at 04:06