Influence of anionic and cationic polyelectrolytes on the conductivity and morphology of poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) films

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Dimitar Valtakari, Roger Bollström, Martti Toivakka, Jarkko J. Saarinen
Förläggare: ELSEVIER SCIENCE SA
Publiceringsår: 2015
Tidskrift: Thin Solid Films
Tidskriftsakronym: THIN SOLID FILMS
Volym: 590
Artikelns första sida, sidnummer: 170
Artikelns sista sida, sidnummer: 176
Antal sidor: 7
ISSN: 0040-6090
eISSN: 1879-2731


Abstrakt

Conductivity of the poly(3,4-ethylenedioxythiophene):poly(styrenesulfonate) (PEDOT:PSS) strongly depends on the film morphology, which can be altered by the presence of polyelectrolytes. Aqueous dispersion of PEDOT:PSS was studied with anionic sodium polyacrylate (PA) and cationic poly(dimethyldiallylammonium chloride) (pDADMAC) polyelectrolytes that are typically used in papermaking as retention aids and dispersing agents in the paper pigment coating formulations. Spin-coated PEDOT:PSS films on a PA coated glass formed non-uniform layers with lowered conductivity compared to the reference PEDOT:PSS films on a clean glass substrate. On contrary, spin-coated PEDOT:PSS on a pDADMAC coated glass formed uniform layers with good conductivity. These results point out the importance of surface chemistry when using renewable and recyclable paper-based substrates with the PEDOT:PSS films.


Nyckelord

Conductivity, Paper, PEDOT:PSS, Printed functionality

Senast uppdaterad 2019-25-08 vid 06:56