Isomerization of α-pinene oxide using Fe-supported catalysts: Selective synthesis of campholenic aldehyde

A1 Journal article (refereed)


Internal Authors/Editors


Publication Details

List of Authors: Martina Stekrova, Narendra Kumar, Atte Aho, Ilia Sinev, Wolfgang Grünert, Johnny Dahl, Jorma Roine, Sergey S. Arzumanov, Päivi Mäki-Arvela, Dmitry Yu. Murzin
Publication year: 2014
Journal: Applied Catalysis A: General
Volume number: 470
Start page: 162
End page: 176
eISSN: 1873-3875


Abstract

α-Pinene oxide, an oxygenated derivative of α-pinene, can be converted into various valuable substances useful as flavour, fragrance and pharmaceutical compounds. Campholenic aldehyde is one of the most desired products of α-pinene oxide isomerization being a valuable intermediate for the production of sandalwood-like fragrances. Iron modified zeolites Beta-75 and ZSM-5, mesoporous material MCM-41, silica and alumina were prepared by two methods (impregnation and solid-state ion exchange) and tested for selective preparation of campholenic aldehyde by isomerization of α-pinene oxide. The characterization of tested catalyst was carried out using scanning electron microscope analysis, nitrogen adsorption measurements, pyridine adsorption–desorption with FTIR, X-ray absorption spectroscopy measurements, XPS-analysis, 29Si MAS NMR and 27Al MAS NMR and X-ray diffraction. The isomerization of α-pinene oxide was carried out in toluene as a solvent at 70 °C. The main properties influencing the activity and the selectivity are the acidic and structural properties of the tested catalysts. The highest selectivity of 66% was achieved at complete conversion of α-pinene oxide with Fe-MCM-41.

Last updated on 2019-14-11 at 03:32