Er³⁺-Al₂O₃ nanoparticles doping of borosilicate glass

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Jonathan Massera, Laeticia Petit, Joona Koponen, Benoit Glorieux, Leena Hupa, Mikko Hupa
Publiceringsår: 2015
Tidskrift: Bulletin of Materials Science
Volym: 38
Nummer: 5
Artikelns första sida, sidnummer: 1407
Artikelns sista sida, sidnummer: 1410
eISSN: 0973-7669


Abstrakt

Novel borosilicate glasses were developed by adding in the glass batch Er3+-Al2O3 nanoparticles synthetized by using a soft chemical method. A similar nanoparticle doping with modified chemical vapour deposition (MCVD) process was developed to increase the efficiency of the amplifying silica fibre in comparison to using MCVD and solution doping. It was shown that with the melt quench technique, a Er3+-Al2O3 nanoparticle doping neither leads to an increase in the Er3+ luminescence properties nor allows one to control the rare-earth chemical environment in a borosilicate glass. The site of Er3+ in the Er3+-Al2O3 nanoparticle containing glass seems to be similar as in glasses with the same composition prepared using standard raw materials. We suspect the Er3+ ions to diffuse from the nanoparticles into the glass matrix. There was no clear evidence of the presence of Al2O3 nanoparticles in the glasses after melting.

Senast uppdaterad 2019-19-11 vid 03:34