Synthesis of chiral phosphorous and phosphoric acid derivatives from the lignans matairesinol and conidendrin

A1 Originalartikel i en vetenskaplig tidskrift (referentgranskad)


Interna författare/redaktörer


Publikationens författare: Yury Brusentsev, Patrik Eklund
Förläggare: Georg Thieme Verlag KG
Publiceringsår: 2016
Tidskrift: Synlett
Volym: 27
Nummer: 18
Artikelns första sida, sidnummer: 2557
Artikelns sista sida, sidnummer: 2560
eISSN: 1437-2096


Abstrakt

Methods for the preparation of phosphites and phosphates from chiral diols based on lignan backbones were developed. Four novel phosphites and one phosphate were synthesized and characterized. Sterically hindered diols showed diastereoselectivity in formations of phosphites, whereas non-hindered diols showed no selectivity.


Nyckelord

chiral 1,4-diols, chiral phosphates, chiral phosphites, chiral pool, conidendrin, Lignan, matairesinol

Senast uppdaterad 2020-14-07 vid 06:02